Here's a new one for me. I have a MacBook Pro i5 A1278 that only charges when the computer is on. As soon as it shuts down the computer won't charge. I tried to do an SMC reset and have been unable to change the light on the charger when attempting. The logic board doesn't show a drop of liquid damage. Have you seen this before? Do you know where the SMC chip is on the logic board?
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When you say it's not charging when it's off, have you left it connected overnight, and then powered up and checked the battery with Coconut Battery or iStat Pro? When it's off, do you get a blinking light when you press the battery indicator light?
Odd indeed.